128672-62-8Relevant articles and documents
ALKYLATION OF ?-DONATING COMPOUNDS BY METHOXYALLENE-ARYLSULPHENYLCHLORIDE ADDUCTS
Smolyakova, I. P.,Smit, V. A.,Lutsenko, A. I.,Daeva, E. D.
, p. 101 - 107 (2007/10/02)
Reaction of methoxyallene with arylsulphenyl chlorides proceeds nonselectively with formation of mixtures of 1,2- and 2,3-arylthiochloro adducts, the composition of which depends on the nature of the reagent and solvent. ?-Donating compounds of various types in the presence of Lewis acids are alkylated by adducts of methoxyallene with arylsulphenyl chlorides and primarily products are formed by attack at the C3 atom of the reagent.