128856-03-1

Basic information

• Product Name: 4-(1-trifluoromethyl-2-chloroethylthio)-6-oxatricyclo<3.2.1.1^3,8>nonan-7-one
• Synonyms: 4-(1-trifluoromethyl-2-chloroethylthio)-6-oxatricyclo<3.2.1.1^3,8>nonan-7-one
• CAS NO: 128856-03-1
• Molecular Weight: 300.729
• Mol File: 128856-03-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-(1-trifluoromethyl-2-chloroethylthio)-6-oxatricyclo<3.2.1.1^3,8>nonan-7-one(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(1-trifluoromethyl-2-chloroethylthio)-6-oxatricyclo<3.2.1.1^3,8>nonan-7-one(128856-03-1)
• EPA Substance Registry System: 4-(1-trifluoromethyl-2-chloroethylthio)-6-oxatricyclo<3.2.1.1^3,8>nonan-7-one(128856-03-1)

Safety Data

• Hazardous Substances Data: 128856-03-1(Hazardous Substances Data)

Upstream product

• 120-74-1 endo-norbornenecarboxylic acid 
• 87612-17-7 α-Trifluoromethyl-β-chloroethylsulfenyl chloride 
• 57122-22-2 bis<(S)-1-phenylethyl>carbodiimide 

Relevant articles and documents

Zirconocene-catalyzed cationic Diels-Alder reactions

In situ prepared Cp2ZrCl+ catalyzes the formation of dioxolenium ions from α,β-unsaturated epoxy esters. As a consequence of this activation process, acrylate, methacrylate and crotonate derivatives undergo a rapid and stereoselective cationic [4+2] cycloaddition with a wide range of dienes. Ring-extended carboxylic acid derivatives are formed in 1-7 h at 0-21°C and in 50-90% yield after saponification of the intermediate diol esters. Simple Lewis acid catalysis by Cp2ZrCl+ can be excluded on the basis of the experimental results.