1290542-49-2

Basic information

• Product Name: methyl 4-(6-cyanonaphthalen-2-yl)benzoate
• Synonyms: methyl 4-(6-cyanonaphthalen-2-yl)benzoate
• CAS NO: 1290542-49-2
• Molecular Weight: 287.318
• Mol File: 1290542-49-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 4-(6-cyanonaphthalen-2-yl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-(6-cyanonaphthalen-2-yl)benzoate(1290542-49-2)
• EPA Substance Registry System: methyl 4-(6-cyanonaphthalen-2-yl)benzoate(1290542-49-2)

Safety Data

• Hazardous Substances Data: 1290542-49-2(Hazardous Substances Data)

Upstream product

• 99768-12-4 4-methoxycarbonylphenylboronic acid 
• 52927-22-7 6-cyano-2-naphthol 

Relevant articles and documents

An efficient suzuki-miyaura coupling of aryl sulfamates and boronic acids catalyzed by NiCl2(dppp)

The Suzuki-Miyaura cross-coupling of aryl sulfamates and boronic acids was investigated by using [1,3-bis(diphenylphosphanyl)propane]nickel(II) chloride {NiCl2(dppp)} as the catalyst. The results showed that NiCl 2(dppp) is a highly active and general catalyst that allows effective Suzuki-Miyaura cross-coupling of aryl sulfamates with a slight excess amount of the boronic acid (1.2 equiv.) in the presence of a low catalyst loading (generally 1.0-1.5 mol-%). The method also displays broad generality not only to various aryl sulfamates, but also to an array of boronic acids. Furthermore, various functional groups are tolerated. These apparent advantages make NiCl2(dppp) a practical and reliable catalyst system for the Suzuki-Miyaura coupling of aryl sulfamates.