129077-51-6

Basic information

• Product Name: 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE
• Synonyms: 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE
• CAS NO: 129077-51-6
• Molecular Formula: C₂₁H₁₄N₄O₂
• Molecular Weight: 354.36
• Mol File: 129077-51-6.mol
• Article Data: 19

Chemical Properties

• Melting Point: 158-159 °C(Solv: ethanol (64-17-5))
• Boiling Point: 536.1 °C at 760 mmHg
• Flash Point: 278 °C
• Appearance: /
• Density: 1.28 g/cm³
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• PKA: 4.41±0.22(Predicted)
• CAS DataBase Reference: 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE(129077-51-6)
• EPA Substance Registry System: 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE(129077-51-6)

Safety Data

• Hazardous Substances Data: 129077-51-6(Hazardous Substances Data)

Usage

General Description

4'-(4-nitrophenyl)-2,2':6',2''-terpyridine is a chemical compound with the molecular formula C27H18N4O2. It is a terpyridine derivative with a 4-nitrophenyl group attached to the 4' position on the terpyridine core. 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE is commonly used in coordination chemistry and material science due to its unique electronic and photophysical properties. It has been studied for its potential applications in luminescent materials, sensors, and as a building block for supramolecular assemblies. Its specific properties and applications make it a useful tool for researchers in various fields of chemistry and material science.

Upstream product

• 1122-62-9 2-acetylpyridine 
• 555-16-8 4-nitrobenzaldehdye 
• 1121-60-4 pyridine-2-carbaldehyde 
• 134653-69-3 4'-{[(Trifluoromethyl)sulfonyl]oxy}-2,2':6',2''-terpyridine 
• 502622-85-7 5,5-dimethyl-2-(4-nitrophenyl)-1,3,2-dioxaborinane 
• 636-98-6 p-nitrobenzene iodide 
• 381218-94-6 4'-((neopentyl glycolato)boron)-2,2':6',2''-terpyridine 
• 149817-62-9 4'-bromo-2,2':6',2''-terpyridine 
• 26482-00-8 1-(2-oxo-2-(2-pyridyl)ethyl)pyridinium iodide 
• 18451-69-9 (2E)-3-(4-nitrophenyl)-1-(pyridin-2-yl)prop-2-en-1-one 

Downstream Products

• 870814-18-9 [IrCl₃(4'-(phenyl-p-nitro)-2,2':6',2''-terpyridine)] 
• 1073314-51-8 4'-(N-(4-(2,4-dioxopentan-3-yl)phenyl)benamide)2,2':6',2''-terpyridine 
• 870814-19-0 [Ir(4-ethylbenzoate)3(4'-(phenyl-p-nitro)-2,2':6',2''-terpyridine)] 
• 1309474-97-2 (C₅H₄N)2C₅H₂NC₆H₄NHCOCH₂CH₂C₄NH(CH₃)(COOH)CONHC(NH₂)2⁽¹⁺⁾*Cl^(1-)=[C₃₂H₂₉N₈O₄]Cl 

Relevant articles and documents

Optimising the synthesis, polymer membrane encapsulation and photoreduction performance of Ru(II)- and Ir(III)-bis(terpyridine) cytochrome c bioconjugates

Ruthenium(ii) and iridium(iii) bis(terpyridine) complexes were prepared with maleimide functionalities in order to site-specifically modify yeast iso-1 cytochrome c possessing a single cysteine residue available for modification (CYS102). Single X-ray crystal structures were solved for aniline and maleimide Ru(ii) 3 and Ru(ii) 4, respectively, providing detailed structural detail of the complexes. Light-activated bioconjugates prepared from Ru(ii) 4 in the presence of tris(2-carboxyethyl)-phosphine (TCEP) significantly improved yields from 6% to 27%. Photoinduced electron transfer studies of Ru(ii)-cyt c in bulk solution and polymer membrane encapsulated specimens were performed using EDTA as a sacrificial electron donor. It was found that membrane encapsulation of Ru(ii)-cyt c in PS140-b-PAA48 resulted in a quantum efficiency of 1.1 ± 0.3 × 10-3, which was a two-fold increase relative to the bulk. Moreover, Ir(iii)-cyt c bioconjugates showed a quantum efficiency of 3.8 ± 1.9 × 10-1, equivalent to a ～640-fold increase relative to bulk Ru(ii)-cyt c.

Facile synthesis and photochromic properties of diarylethene-containing terpyridine and its transition metal (Zn2+/Co2+/Ru 2+) complexes

Several transition metal complexes based on 2,3-bis(2,4,5-trimethyl-3- thienyl)maleic anhydride (DTE) bearing terpyridine (TPY) have been designed and synthesized. Furthermore, the photochromism of the free ligand and the influence of transition metal moi

Aggregation induced emission (AIE) active 4-amino-1,8-naphthalimide-Tr?ger's base for the selective sensing of chemical explosives in competitive aqueous media

The 4-amino-1,8-naphthalimide-Tr?ger's base fluorophore, TBNap-TPy, adorned with phenyl-terpyridine moiety was synthesised and assessed for its aggregation-induced emission (AIE) behaviour. TBNap-TPy was further employed as a fluorescent sensor for the di

Palladium supported terpyridine modified magnetic nanoparticles as an efficient catalyst for carbon-carbon bond formation

In this paper, a novel catalyst is designed, synthesized and characterized based on the functionalization of magnetic iron oxide nanoparticles by terpyridine as a ligand for the immobilization of palladium. The catalyst is fully characterized by several c

Surface bottom-up fabrication of porphyrin-terminated metal complex molecular wires with photo-electron conversion properties on ITO

We fabricated photoelectron conversion system with porphyrin-terminated "molecular wires" on an ITO surface synthesized using stepwise metal-terpyridine complexation reactions. The efficiency and the electrode potential singniflcantly depended on the meta