1293991-08-8Relevant articles and documents
Enol silyl ethers via copper(II)-catalyzed C-O bond formation
Chan, Daniel G.,Winternheimer, David J.,Merlic, Craig A.
supporting information; experimental part, p. 2778 - 2781 (2011/08/02)
Copper(II) acetate catalyzes the coupling of pinacol vinylboronates with silanols producing enol silyl ethers. This represents a novel enol silyl ether synthesis via formation of the C-O bond instead of the conventional Si-O bond. This also constitutes the first transition-metal-catalyzed oxidative cross-coupling with silanols.