1295502-20-3Relevant articles and documents
Facile synthesis of a narrow-bandgap strong-donor-alt-strong-acceptor copolymer of poly(5,6-difluorobenzo-[c][1,2,5]-thiadiazole-alt-5H-dithieno[3,2-b:2′,3'-d]pyran) via direct C-H arylation polymerization
Efrem, Amsalu,Wang, Kai,Wang, Mingfeng
, p. 331 - 338 (2017/06/20)
A narrow bandgap D-A conjugated polymer based on 5H-dithieno [3,2-b:2′,3'-d]pyran alternating with 5,6-difluoro-2,1,3-benzothiadiazole (denoted as PDFBT-alt-DTP) was synthesized via direct C-H arylation polymerization (DAP) as an atomically efficient protocol. The optimal reaction condition for the DAP gave the target polymers with moderate number-average molecular weights (Mn) using optimized catalytic condition of Pd2 (dba)3/(o-MeOPh)3P/PivOH/K2CO3 in o-xylene. UV-vis-NIR absorption spectra of the obtained polymers show the presence of aggregation and interchain interaction in thin films. 1H-NMR spectroscopic analysis indicates good C-H selectivity corresponding to an alternating strong-donor-alt-strong-acceptor conjugated backbone. The hole mobility of the resulting polymers in a magnitude of 10?4 cm2V?1s?1 was reached in bottom-gate top-contact field-effect transistors fabricated and tested under ambient conditions.
Compound used for forming high-molecular compound
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, (2016/10/08)
The present invention provides a macromolecular compound by which the short-circuit current density and the photoelectric conversion efficiency are enhanced when the macromolecular compound is used in an organic layer contained in a photovoltaic cell. Specifically, the present invention provides a macromolecular compound having a structural unit represented by Formula (5): wherein R52 and R53 are the same as or different from each other and represent hydrogen atoms, halogen atoms, alkyl groups, alkyl oxygen radicals, alkyl sulfonium, aryl groups, aryl oxygen radicals, aryl sulfonium, aryl alkyl, aryl alkyl oxygen radicals, acyl groups, acyloxy, acylamino, imide groups, amidogen, substituted amino, substituted silicyl, substituted silicon alkyl oxygen radicals, substituted silicon alkyl harvard, silicon alkyl amine, univalent heterocyclic radical, heterocyclic oxygen radicals, heterocyclic sulfonium, aryl alkenyl, aryl alkynyl, carboxyl or cyan; W1 and W2 are the same as or different from each other and represent hydrogen atoms, halogen atoms, alkyl sulfonate base, aryl sulfonic acid ester base, aryl alkyl sulfonate base, boric acid ester residues, matte methyl, scales base, Phosphonic acid ester methyl, single halogenated methyl, boric acid residues, formyl groups, vinyl or organic tin residues.
METAL COMPLEXES AND ORGANIC SOLAR CELL COMPRISING THE SAME
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, (2016/10/08)
The present invention provides a metal complex, which comprises a structure represented by chemical formula 1, and an organic solar cell including the same.COPYRIGHT KIPO 2016