1296645-36-7

Basic information

• Product Name: C₁₈H₂₉BrO₂
• Synonyms: C₁₈H₂₉BrO₂
• CAS NO: 1296645-36-7
• Molecular Weight: 357.331
• Mol File: 1296645-36-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₈H₂₉BrO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₈H₂₉BrO₂(1296645-36-7)
• EPA Substance Registry System: C₁₈H₂₉BrO₂(1296645-36-7)

Safety Data

• Hazardous Substances Data: 1296645-36-7(Hazardous Substances Data)

Upstream product

• 100-51-6 benzyl alcohol 

Downstream Products

• 53463-68-6 1-bromo-10-decanol 

Relevant articles and documents

The reaction of acetal-type protective groups in combination with TMSOTf and 2,2′-bipyridyl; Mild and chemoselective deprotection and direct conversion to other protective groups

A mild and chemoselective deprotection method of various acetal-type protective groups, such as MOM, MEM, BOM, and SEM ethers, has been developed. The combination of TMSOTf and 2,2′-bipyridyl was very effective for the deprotection, and the reaction proceeded via the formation of pyridinium intermediates, which were hydrolyzed to the corresponding alcohols in good to high yields. The features of this method are mild (almost neutral) reaction conditions and the tolerability of acid-sensitive functional groups. This method is also applicable for the direct conversion of MOM ether to BOM or SEM ether using the appropriate alcohols instead of H2O.