1299358-21-6

Basic information

• Product Name: (1S,2S)-5-(benzyloxy)-1-ethyl-2-methyl-3-oxopentyl bromoacetate
• Synonyms: (1S,2S)-5-(benzyloxy)-1-ethyl-2-methyl-3-oxopentyl bromoacetate
• CAS NO: 1299358-21-6
• Molecular Weight: 371.271
• Mol File: 1299358-21-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2S)-5-(benzyloxy)-1-ethyl-2-methyl-3-oxopentyl bromoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S)-5-(benzyloxy)-1-ethyl-2-methyl-3-oxopentyl bromoacetate(1299358-21-6)
• EPA Substance Registry System: (1S,2S)-5-(benzyloxy)-1-ethyl-2-methyl-3-oxopentyl bromoacetate(1299358-21-6)

Safety Data

• Hazardous Substances Data: 1299358-21-6(Hazardous Substances Data)

Upstream product

• 109715-82-4 methyl (2S,3S)-3-(tert-butyldimethylsilyloxy)-2-methylpentanoate 
• 42558-50-9 methyl (S)-3-hydroxyvalerate 
• 30414-53-0 methyl propanoyl acetate 
• 1299358-18-1 (4S,5S)-1-(benzyloxy)-5-{[tert-butyl(dimethyl)silyl]oxy}-4-methylheptan-3-one 
• 1299358-14-7 (4S,5S)-5-{[tert-butyl(dimethyl)silyl]oxy}-4-methylhept-1-en-3-one 
• 22118-09-8 2-bromoacetyl chloride 
• 1299358-19-2 (4S,5S)-1-(benzyloxy)-5-hydroxy-4-methylheptan-3-one 

Downstream Products

• 1299358-22-7 (4R,5S,6S)-4-(2-(benzyloxy)ethyl)-6-ethyl-4-hydroxy-5-methyl-tetrahydropyran-2-one 
• 1299358-23-8 (4R,5S,6S)-4-(2-(benzyloxy)ethyl)-6-ethyl-5-methyl-4-(trimethylsilyloxy)-tetrahydropyran-2-one 
• 1299358-26-1 (4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylthio)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one 
• 1299358-29-4 (4S,5S,6S)-6-ethyl-5-methyl-4-(2-(1-phenyl-1H-tetrazol-5-ylsulfonyl)ethyl)-4-(trimethylsilyloxy)-tetrahydropyran-2-one 

Relevant articles and documents

Synthetic studies towards leiodermatolide: Rapid stereoselective syntheses of key fragments

The synthesis of three key fragments of the novel 16-membered macrolide leiodermatolide is described. The stereotetrad-containing building block was prepared via a Marshall-Tamaru reaction on an aldehyde obtained by organocatalysis. For a second building block, a Marshall-Tamaru reaction was used as well. The side-chain fragment containing a hydroxy δ-lactone could be obtained by intramolecular Reformatsky reaction. Georg Thieme Verlag Stuttgart.