129976-61-0Relevant articles and documents
Ozonolsysis of 1,4-disubstituted 1,3-cyclohexadienes and of related compounds in methanol
Griesbaum, Karl,Mertens, Henri,Jung, In Chang
, p. 1369 - 1375 (2007/10/02)
Ozonolysis of 1,4-dimethyl- (5a) and 1-methyl-4-isopropyl-1,3-cyclohexadiene (5b) in methanol occur stepwise by sequential cleavage of the two double bonds.Monoozonolysis products are the corresponding compounds 6 and 7, and diozonolysis products are the corresponding cyclic peroxides 19, 20, and 21.By contrast, ozonolysis of the non-conjugated diene 2,5-dimethyl-1,5-hexadiene (13) in methanol occurs by simultaneous mono- and diozonolysis to give 14, 16a, 18a, and 20a.