13027-70-8

Basic information

• Product Name: Isopropyl-α-phenyl-α-isopropylacetat
• Synonyms: Isopropyl-α-phenyl-α-isopropylacetat
• CAS NO: 13027-70-8
• Molecular Weight: 220.312
• Mol File: 13027-70-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Isopropyl-α-phenyl-α-isopropylacetat(CAS DataBase Reference)
• NIST Chemistry Reference: Isopropyl-α-phenyl-α-isopropylacetat(13027-70-8)
• EPA Substance Registry System: Isopropyl-α-phenyl-α-isopropylacetat(13027-70-8)

Safety Data

• Hazardous Substances Data: 13027-70-8(Hazardous Substances Data)

Upstream product

• 3508-94-9 3-methyl-2-phenylbutyric acid 
• 51631-26-6 α-isopropyl-α-phenylacetyl chloride 
• 67-63-0 isopropyl alcohol 
• 4861-85-2 isopropyl phenylacetate 

Downstream Products

• 851166-04-6 ((Z)-1-Isopropoxy-3-methyl-2-phenyl-but-1-enyloxy)-trimethyl-silane 

Relevant articles and documents

Catalytic enantioselective construction of all-carbon quaternary stereocenters: Synthetic and mechanistic studies of the C-acylation of silyl ketene acetals

With the aid of an appropriate chiral catalyst, acyclic silyl ketene acetals react with anhydrides to furnish 1,3-dicarbonyl compounds that bear all-carbon quaternary stereocenters in good ee and yield. Mechanistic studies provide strong support for a catalytic cycle that involves activation of both the electrophile (anhydride → acylpyridinium) and the nucleophile (silyl ketene acetal → enolate).