13040-77-2Relevant articles and documents
Novel DNA binding agents: Hydrazone-based helical trinuclear Ag complexes
Cheng, Chien-Chung,Hung, Sue-Mei,Yeh, Chia-Yi,Chang, Chen-Shen,Wang, Wen-Jwu
, p. 189 - 192 (2003)
Using the hydrazone linker and the self-assembly, functionalized Ag complexes with a helical structure showed a 2.96 A distance between metal-metal bonds, well-aligned aromatic rings, and the strong affinity toward DNA.
Micelle-Enabled Suzuki-Miyaura Cross-Coupling of Heteroaryl Boronate Esters
Guo, Pengfei,Zhang, Hao,Zhou, Jianguang,Gallou, Fabrice,Parmentier, Michael,Wang, Hui
, p. 7523 - 7527 (2018)
We report a micellar protocol for Suzuki-Miyaura cross-coupling of heteroaryl boronic esters with aryl or heteroaryl halides. The micellar catalysis enables this coupling reaction to run under mild conditions, which avoids the decomposition of heteroaryl boronate esters and allows for high chemoselectivity for cross-coupling reaction with 6-chloropridine-2-boronic ester. The micellar protocol expands the scope of the cross-coupling reaction with challenging heteroaryl boronic esters and complements the existing cross-coupling methods for construction of heterobiaryl building blocks.
METHOD FOR COUPLING HALOGENATED PYRIDINE COMPOUND WITH HALOGENATED AROMATIC COMPOUND
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Paragraph 0054; 0055, (2020/10/20)
There is a demand for the development of a technique according to which a reaction for coupling a halogenated pyridine compound with a halogenated aromatic compound can be performed in a simple manner through a small number of steps without using expensive agents such as a palladium catalyst. A method for coupling a halogenated pyridine compound with a halogenated aromatic compound includes a step of coupling a halogenated pyridine compound with a halogenated aromatic compound to obtain a pyridine compound by reacting, in a reaction solvent, the halogenated pyridine compound and the halogenated aromatic compound with a solution containing an alkali metal.