130608-06-9

Basic information

• Product Name: Benzenepropanoic acid, a-[[(4-nitrophenyl)sulfonyl]oxy]-, methyl ester, (S)-
• CAS NO: 130608-06-9
• Molecular Formula: C16H15NO7S
• Molecular Weight: 365.364
• Mol File: 130608-06-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenepropanoic acid, a-[[(4-nitrophenyl)sulfonyl]oxy]-, methyl ester, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanoic acid, a-[[(4-nitrophenyl)sulfonyl]oxy]-, methyl ester, (S)-(130608-06-9)
• EPA Substance Registry System: Benzenepropanoic acid, a-[[(4-nitrophenyl)sulfonyl]oxy]-, methyl ester, (S)-(130608-06-9)

Safety Data

• Hazardous Substances Data: 130608-06-9(Hazardous Substances Data)

Upstream product

• 13673-95-5 (S)-methyl 2-hydroxy-3-phenylpropanoate 
• 98-74-8 4-Nitrobenzenesulfonyl chloride 

Downstream Products

• 130608-09-2 (R)-2-(N'-tert-Butoxycarbonyl-hydrazino)-3-phenyl-propionic acid methyl ester 
• 150447-60-2 H-(N²-Boc)aPhe-OMe 
• 14381-08-9 (R)-2-(N'-tert-Butoxycarbonyl-hydrazino)-3-phenyl-propionic acid 
• 40248-79-1 (R)-2-Hydrazino-3-phenyl-propionic acid methyl ester 
• 124790-74-5 (R)-2-azido-3-phenylpropionic acid methyl ester 
• 116911-32-1 (S)-2-azido-3-phenylpropionic acid methyl ester 

Relevant articles and documents

THE PREPARATION OF 2-HYDRAZINYL ESTERS IN HIGH OPTICAL PURITY FROM 2-SULFONYLOXY ESTERS

Chiral 2-triflyloxy esters, prepared from chiral 2-hydroxy esters, react enantiospecifically with BocNHNH2 to produce optically pure 2-hydrazinyl ester derivatives in high yields.The reaction of 2-nosyloxy esters with BocNHNH2 gives 2-(Boc-hydrazinyl) esters, thus providing an efficient (albeit slow) method for the conversion of esters to 2-hydrazinyl ester derivatives.