1306748-23-1

Basic information

• Product Name: (E)-methyl N-(1,3-diphenylallyl)sulfamate
• Synonyms: (E)-methyl N-(1,3-diphenylallyl)sulfamate
• CAS NO: 1306748-23-1
• Molecular Weight: 303.382
• Mol File: 1306748-23-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-methyl N-(1,3-diphenylallyl)sulfamate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-methyl N-(1,3-diphenylallyl)sulfamate(1306748-23-1)
• EPA Substance Registry System: (E)-methyl N-(1,3-diphenylallyl)sulfamate(1306748-23-1)

Safety Data

• Hazardous Substances Data: 1306748-23-1(Hazardous Substances Data)

Upstream product

• 55665-95-7 sulfamic acid methyl ester 
• 62668-02-4 (E)-1,3-diphenyl-2-propen-1-ol 

Relevant articles and documents

Intermolecular amination of allyl alcohols with sulfamates: Effective utilization of mercuric catalyst

Herein, we describe the intermolecular amination of allyl alcohols with sulfamates, which have been underutilized as nitrogen nucleophiles for allylic amination. Methyl sulfamate is a good nucleophile in the presence of mercuric triflate and efficiently generates monoallylation products in excellent yield at room temperature. Furthermore, the solid-supported mercuric catalyst silaphenyl mercuric triflate also showed remarkable catalytic activity for the allylic amination. Intermolecular amination of allyl alcohol with sulfamate as a modifiable nitrogen nucleophile is presented. Mercuric reagents act as highly efficient catalyst for the allylic amination, and the procedure was applied to the preparation of various amine derivatives. In many cases, the reaction can be carried out at room temperature and is applicable to a large range of allylic alcohols to give the monoallylated products in excellent yield. Copyright