130718-61-5

Basic information

• Product Name: Acetic acid (2R,3R,4S)-4-acetoxy-2-acetoxymethyl-5-bromo-6-phenoxythiocarbonyloxy-tetrahydro-pyran-3-yl ester
• Synonyms: Acetic acid (2R,3R,4S)-4-acetoxy-2-acetoxymethyl-5-bromo-6-phenoxythiocarbonyloxy-tetrahydro-pyran-3-yl ester
• CAS NO: 130718-61-5
• Molecular Weight: 505.34
• Mol File: 130718-61-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid (2R,3R,4S)-4-acetoxy-2-acetoxymethyl-5-bromo-6-phenoxythiocarbonyloxy-tetrahydro-pyran-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (2R,3R,4S)-4-acetoxy-2-acetoxymethyl-5-bromo-6-phenoxythiocarbonyloxy-tetrahydro-pyran-3-yl ester(130718-61-5)
• EPA Substance Registry System: Acetic acid (2R,3R,4S)-4-acetoxy-2-acetoxymethyl-5-bromo-6-phenoxythiocarbonyloxy-tetrahydro-pyran-3-yl ester(130718-61-5)

Safety Data

• Hazardous Substances Data: 130718-61-5(Hazardous Substances Data)

Upstream product

• 1005-56-7 phenylcarbonochloridothioate 
• 1190753-99-1 Acetic acid (2R,3R,4S)-4-acetoxy-2-acetoxymethyl-5,6-dibromo-tetrahydro-pyran-3-yl ester 

Downstream Products

• 2873-29-2 D-glucal triacetate 

Relevant articles and documents

A REGIOSPECIFIC SYNTHESIS OF UNSATURATED NUCLEOSIDES, CARBOHYDRATES AND OTHER OLEFINS

Vicinal disubstituted nucleosides, carbohydrates and cyclohexane derivatives with a pair of radical leaving groups, such as chloro, bromo, phenoxythiocarbonyloxy, and imidazolylthiocarbonyloxy groups, have been successfully converted to the corresponding olefins in high yields (60-90 percent) without observed side products, by reaction with tri-n-butyltin hydride and azobisisobutyronitrile in an appropriate solvent.