130755-47-4

Basic information

• Product Name: (dichlorofluoromethyl)(phenyl)sulfide
• Synonyms: (dichlorofluoromethyl)(phenyl)sulfide
• CAS NO: 130755-47-4
• Molecular Weight: 211.087
• Mol File: 130755-47-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (dichlorofluoromethyl)(phenyl)sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: (dichlorofluoromethyl)(phenyl)sulfide(130755-47-4)
• EPA Substance Registry System: (dichlorofluoromethyl)(phenyl)sulfide(130755-47-4)

Safety Data

• Hazardous Substances Data: 130755-47-4(Hazardous Substances Data)

Upstream product

• 75-69-4 trichlorofluoromethane 
• 882-33-7 diphenyldisulfane 
• 701-65-5 (trichloromethylthio)benzene 

Downstream Products

• 140243-94-3 1-chloro-1-fluoromethyl phenyl sulfone 
• 140137-89-9 chlorofluoromethyl phenyl sulfoxide 
• 5433-76-1 diphenylmethyl phenyl sulfone 
• 19523-24-1 1-methyl-4-((phenylsulfonyl)methyl)benzene 
• 3112-88-7 Benzyl phenyl sulfone 
• 78725-90-3 S-phenyl-O-ethyl thiolcarbonate 
• 1334160-30-3 (dichlorofluoromethyl)(imino)(phenyl)-λ⁶-sulfanone 
• 1334160-28-9 N-(acetyl) dichlorofluoromethyl phenyl sulfoximine 
• 331463-16-2 (dichloro-fluoro-methanesulfonyl)-benzene 
• 882-33-7 diphenyldisulfane 
• 116109-54-7 chlorofluoromethyl phenyl sulfide 
• 100-68-5 methyl-phenyl-thioether 
• 331463-24-2 1-chloro-1-fluoro-1-phenylsulfonyl-2-heptanol 
• 331463-26-4 1-chloro-1-fluoro-1-phenylsulfonyl-4-methyl-2-pentanol 

Relevant articles and documents

Microwave-assisted aliphatic fluorine-chlorine exchange using triethylamine trihydrofluoride (TREAT-HF)

Aliphatic fluorine-chlorine exchange reactions can be performed under microwave conditions using TREAT-HF as a mild and selective fluorination reagent. The highly polar TREAT-HF couples efficiently with microwave irradiation and reaction temperatures of 250 °C can be reached within 30 s. Under these conditions dichloromethyl- and trichloromethyl substrates can be converted into the corresponding fluoro analogs within 5 min. In order to prevent corrosion of borosilicate reaction vessel at high temperatures the use of sintered silicon carbide microwave vials is introduced.

Process for the preparation of perhaloalkylthioethers

The present invention relates to a process for the preparation of perhaloalkylthioethers by bringing a perhaloalkyl halide, preferably a bromide or an iodide, into contact with a disulphide in the presence of zinc and of sulphur dioxide or of a dithionite or of a hydroxymethanesulphinate or of a formate anion and sulphur dioxide.