1308331-91-0Relevant articles and documents
Asymmetric aldol-Tishchenko reaction catalyzed by Yb-complexes with basic amino acid-derived ligands
Stodulski, MacIej,Maminska, Agnieszka,Mlynarski, Jacek
experimental part, p. 464 - 467 (2011/05/30)
Simple amino acid-derived esters have been identified as promising chiral sources for the ytterbium-catalyzed aldol-Tishchenko reaction of aromatic aldehydes with aliphatic ketones. The 1,3-anti-diols with three stereogenic centers were isolated in excellent yields, complete anti-diastereocontrol and enantioselectivities of up to 50% ee.