1308659-32-6

Basic information

• Product Name: 8-acetoxy-3-methyleneoct-4-en-2-yl benzoate
• Synonyms: 8-acetoxy-3-methyleneoct-4-en-2-yl benzoate
• CAS NO: 1308659-32-6
• Molecular Weight: 302.37
• Mol File: 1308659-32-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 8-acetoxy-3-methyleneoct-4-en-2-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 8-acetoxy-3-methyleneoct-4-en-2-yl benzoate(1308659-32-6)
• EPA Substance Registry System: 8-acetoxy-3-methyleneoct-4-en-2-yl benzoate(1308659-32-6)

Safety Data

• Hazardous Substances Data: 1308659-32-6(Hazardous Substances Data)

Upstream product

• 1576-85-8 4-pentenyl acetate 
• 29333-27-5 but-3-yn-2-yl benzoate 

Relevant articles and documents

Mild Isomerization of Conjugated Dienes Using Co-Mediated Hydrogen Atom Transfer

A mild and high yielding rearrangement of 1,3-disubstituted-1,3-dienes to 1,1,4-trisubstituted-1,3-dienes using a cobaloxime catalyst and a silane cocatalyst is reported. Chiral centers near the conjugated diene were not racemized. Deuterium labeling studies are consistent with a hydrogen atom transfer mechanism, and radical intermediates were found to be accessible due to the observed ring opening of a cyclopropane ring.