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13089-11-7

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13089-11-7 Usage

Chemical Properties

clear colorless to light yellow liquid

Uses

Methyl 3,3,3-trifluoropyruvate may be used in the synthesis of:2-hydroxy-2-trifluoromethylbutan-4-olides2-(trifluoromethyl)butan-4-olides4-trifluoromethyl-(2H)-pyridazin-3-onesmethyl 3-methoxy-2-trifluoromethylacrylate

General Description

Methyl 3,3,3-trifluoropyruvate is an alkyl 3,3,3-trifluoropyruvate that can be synthesized using hexafluoropropene-1,2-oxide (HFPO) as a starting material. It reacts with aromatic amines, benzylic manoamines and diamines to form the corresponding hemiaminals.

Check Digit Verification of cas no

The CAS Registry Mumber 13089-11-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,0,8 and 9 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 13089-11:
(7*1)+(6*3)+(5*0)+(4*8)+(3*9)+(2*1)+(1*1)=87
87 % 10 = 7
So 13089-11-7 is a valid CAS Registry Number.

13089-11-7 Well-known Company Product Price

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  • Alfa Aesar

  • (B21589)  Methyl trifluoropyruvate, 97%   

  • 13089-11-7

  • 1g

  • 195.0CNY

  • Detail
  • Alfa Aesar

  • (B21589)  Methyl trifluoropyruvate, 97%   

  • 13089-11-7

  • 5g

  • 553.0CNY

  • Detail
  • Alfa Aesar

  • (B21589)  Methyl trifluoropyruvate, 97%   

  • 13089-11-7

  • 25g

  • 2337.0CNY

  • Detail

13089-11-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name METHYL TRIFLUOROPYRUVATE

1.2 Other means of identification

Product number -
Other names Methyl 3,3,3-trifluoropyruvate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13089-11-7 SDS

13089-11-7Related news

Arenesulfonylimines of METHYL TRIFLUOROPYRUVATE (cas 13089-11-7) in the cyclocondensation reactions with 1,3-C,N-and-N,N-binucleophiles09/29/2019

Reaction of arenesulfonylimines of methyl trifluoropyruvate with 1,3-C,N-and-N,N-binucleophiles led to a variety of N-sulfonylated fluorine-containing heterocycles, including the fused ones.detailed

Diethoxyphosphorylimine of METHYL TRIFLUOROPYRUVATE (cas 13089-11-7) in cyclocondensation with 1,3-C,N-and-N,N-binucleophiles09/28/2019

Reaction of diethoxyphosphorylimine of methyl trifluoropyruvate with 1,3-C,N-and-N,N-binucleophiles led to a variety of N-phosphorylated fluorine-containing heterocycles, including the fused ones.detailed

METHYL TRIFLUOROPYRUVATE (cas 13089-11-7) – a new solvent for the production of fluorinated organic resorcinol–formaldehyde aerogels10/01/2019

Resorcinol–formaldehyde aerogels obtained in methyl trifluoropyruvate (MTFP) possess a fluorinated matrix due to the mechanism of electrophilic substitution in the resorcinol moiety with the formation of C–C bond. The use of MTFP as a solvent also substantially accelerates the formaldehyde– r...detailed

METHYL TRIFLUOROPYRUVATE (cas 13089-11-7) Diethoxyphosphorylimine09/27/2019

The first example of trifluoropyruvate phosphorylimines was prepared, and its capability for O- and S-amidoalkylation of water, alcohols, and compounds with the SH function was shown. Phenol and 4-methoxyphenol are O-alkylated, while 3-dimethylaminophenol and indole undergo regiospecific C-alkyl...detailed

Green synthesis of METHYL TRIFLUOROPYRUVATE (cas 13089-11-7) catalyzed by solid acids09/25/2019

Solid acids – NiSO 4 /Al 2 O 3 , Fe 2 (SO 4 ) 3 /Al 2 O 3 and TiO 2 /SO 4 2− – appeared to be effective catalysts for the acid catalyzed synthesis of methyl ester of trifluoropyruvic acid. They are active at 15...detailed

13089-11-7Relevant articles and documents

Green synthesis of methyl trifluoropyruvate catalyzed by solid acids

Lermontov, Sergey A.,Ushakova, Lyudmila L.,Kuryleva, Nina V.

, p. 332 - 334 (2008)

Solid acids - NiSO4/Al2O3, Fe2(SO4)3/Al2O3 and TiO2/SO42- - appeared to be effective catalysts for the acid catalyzed synthesis of met

UNUSUAL REACTION CHEMISTRY IN THERMAL DECOMPOSITION OF ALKALI METAL 2-ALKOXY-2,3,3,3-TETRAFLUOROPROPIONATE SALTS

Pellerite, Mark J.

, p. 43 - 66 (2007/10/02)

Pyrolyses of several salts ROCF(CF3)CO2(-)M(+) (R=Me, Et, CF3CH2; M=Na, K, Cs) have been studied.The reaction chemistry shows highly unusual dependence on the nature of the alkoxy substituent and the metal cation.Product distribution are described along with some proposed mechanisms.

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