1309778-21-9Relevant articles and documents
Rhodium-catalyzed carbene-transfer reactions via thienylcarbene complexes generated from thiocarbamoyl-ene-yne compounds
Tsuneishi, Asuka,Okamoto, Kazuhiro,Ikeda, Yuji,Murai, Masahito,Miki, Koji,Ohe, Kouichi
, p. 655 - 658 (2011)
Catalytic thienylcarbene-transfer reactions have been developed. The rhodium-catalyzed reaction of alkenes, furans, and thiophenes with a thiocarbamoyl-ene-yne compound as a carbene source gave the cyclopropanation products or ring-opened products of heterocycles. These processes provide efficient synthetic methods for thiophene-containing complex molecules. Georg Thieme Verlag Stuttgart - New York.