13101-40-1

Basic information

• Product Name: 1-BROMO-3-CHLORO-5-IODOBENZENE
• Synonyms: 1-BROMO-3-CHLORO-5-IODOBENZENE;3-Bromo-5-chloroiodobenzene
• CAS NO: 13101-40-1
• Molecular Formula: C₆H₃BrClI
• Molecular Weight: 317.35
• Mol File: 13101-40-1.mol
• Article Data: 3

Chemical Properties

• Melting Point: 85.8℃
• Boiling Point: 280.4±25.0℃ (760 Torr)
• Flash Point: 123.4±23.2℃
• Appearance: /
• Density: 2.272±0.06 g/cm3 (20 ºC 760 Torr)
• Vapor Pressure: 0.00644mmHg at 25°C
• Refractive Index: 1.663
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• CAS DataBase Reference: 1-BROMO-3-CHLORO-5-IODOBENZENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-BROMO-3-CHLORO-5-IODOBENZENE(13101-40-1)
• EPA Substance Registry System: 1-BROMO-3-CHLORO-5-IODOBENZENE(13101-40-1)

Safety Data

• Hazardous Substances Data: 13101-40-1(Hazardous Substances Data)

Usage

General Description

1-Bromo-3-chloro-5-iodobenzene is a chemical compound with the molecular formula C6H3BrClI. It is a halogenated aromatic compound, containing bromine, chlorine, and iodine attached to a benzene ring. 1-Bromo-3-chloro-5-iodobenzene is commonly used as a starting material in organic synthesis, particularly in the production of pharmaceuticals and agrochemicals. It is also used in the development of new materials and as a building block for the synthesis of complex organic molecules. The presence of multiple halogens on the benzene ring makes it a versatile compound for creating diverse chemical structures, and it is a valuable tool for researchers and chemists in various fields of study.

InChI:InChI=1/C6H3BrClI/c7-4-1-5(8)3-6(9)2-4/h1-3H

Upstream product

• 96558-78-0 3-bromo-5-chlorophenylamine 
• 108-37-2 1-bromo-3-chlorobenzene 
• 488850-91-5 2-(3-bromo-5-chlorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 14862-52-3 1,3-dibromo-5-chlorobenzene 
• 873386-83-5 2-bromo-6-chloro-4-iodoaniline 
• 873-38-1 4-chloro-2-bromoaniline 
• 71757-16-9 2-bromo-4-chloro-6-iodoaniline 

Downstream Products

• 173678-08-5 1,3-bis(1-naphthyl)-5-(2-naphthyl)benzene 
• 1073062-42-6 2-(3-bromo-5-chlorophenyl )-4,6-diphenyl-1,3,5-triazine 

Relevant articles and documents

COMPOUND, METHOD FOR PREPARING THE SAME, ORGANIC SEMICONDUCTING LAYER, ORGANIC ELECTRONIC DEVICE, DISPLAY DEVICE AND LIGHTING DEVICE COMPRISING THE SAME

The present invention relates to a compound of Formula (I) wherein Ar1 is selected from substituted or unsubstituted C2 to C36heteroaryl and the group Ar1 is bound to the remaining structure represented by Formula (I) via one of its carbon atoms; Ar2 is selected from the group consisting of substituted or unsubstituted C6 to C36aryl and substituted or unsubstituted C4 to C36 heteroaryl comprising at least one heteroatom selected from 0, S and Se, wherein the heteroaryl group comprising at least one heteroatom selected from O, S and Se is bound to the remaining structure represented by Formula (I) via one of its carbon atoms; Ar3 is selected from the group consisting of substituted or unsubstituted C6 to C18 arylene and substituted or unsubstituted C3 to.C18 heteroarylene, wherein it is provided that the group Ar3 comprises not more than three fused rings; wherein, in case that one or more of Ar1, Ar2 and Ar3is substituted, the substituents are each independently selected from the group consisting of D, F, C1 to C20 linear alkyl, C3 to C20branched alkyl, C3 to C20 cyclic alkyl, C1 to C20 linear alkoxy, C3 to C20 branched alkoxy, linear fluorinated C1to C12 allkyl, linear fluorinated C1 to C12 alkoxy, C3 to C12 branched fluorinated cyclic alkyl, C3 to C12 fluorinated cyclic allkyl, C3 to C12 fluorinated cyclic alkoxy, CN, RCN, C6 to C20, aryl, C2 to C20 heteroaryl, OR, SR, (C=0)R, (C=0)NR2, SiR3, (S=0)R, (S=0)2R, (P=0)R2; wherein each R is independently selected from C1to C20 linear alkyl, C1 to C20 alkoxy, C1to C20 thioalkyl, C3to C20 branched alkyl, C3 to C20 cyclic alkyl, C3 to C20 branched alkoxy, C3 to C20 cyclic alkoxy, C3 to C20 branched thioalkyl, C3 to C20 cyclic thioalkyl, C6 to C20 aryl and C2 to C20heteroaryl; and wherein Ar1 and Ar2 are selected differently from each other, a method for preparing the same, an organic semiconducting layer comprising the same, an organic electronic device comprising the same and a display device or a lighting device comprising the organic electronic device.

Sterically controlled iodination of arenes via iridium-catalyzed C-H borylation

A mild method to prepare aryl and heteroaryl iodides by sequential C-H borylation and iodination is reported. The regioselectivity of this process is controlled by steric effects on the C-H borylation step and is complementary to existing methods to form aryl iodides. The iodination of boronic esters has potential for the synthesis of radiolabeled aryl iodides, as demonstrated by the concise synthesis of a potential tracer for SPECT imaging.