131074-16-3Relevant articles and documents
α-Bromoacetophenones in Heterocyclic Synthesis: A Convenient One-Pot Synthesis and the Chemical Behaviour of 3-Bromomethylbenzoisoxazole
Mohareb, Rafat Milad,Sherif, Sherif Mourad,Shams, Hoda Zaki,El-Torgoman, Abdel Moneim
, p. 1067 - 1071 (2007/10/02)
A novel one-pot synthesis of 3-bromomethylbenzoisoxazole (3) utilizing o-hydroxy-α-bromoacetophenone is reported.Coupling of 3 with benzenediazonium chloride afforded, the first reported, C-(3-benzoisoxazolyl)-N-(phenyl)formohydrazidoyl bromide (13).The chemical behaviour of 3 and 13 towards a variety of chemical reagents has been investigated.