1313227-89-2Relevant articles and documents
In Situ Generated Magnesium Cyanide as an Efficient Reagent for Nucleophilic Cyanation of Nitrosoalkenes and Parent Nitronates
Ushakov, Pavel Yu.,Tabolin, Andrey A.,Ioffe, Sema L.,Sukhorukov, Alexey Yu.
, p. 1888 - 1892 (2019)
In situ generated magnesium cyanide [NaCN/Mg(ClO4)2] is suggested as a convenient, readily available, non-volatile and organic-soluble reagent for hydrocyanation reactions. It was successfully used for nucleophilic cyanation of nitrosoalkenes, nitronates, as well as other typical π-electrophiles, such as imines, α,β-unsaturated ketones, alkylidenemalonates and azoalkenes.
3-Halomethylated cyclic nitronates: Synthesis and nucleophilic substitution
Mikhaylov, Andrey A.,Dilman, Alexander D.,Struchkova, Marina I.,Khomutova, Yulia A.,Korlyukov, Alexander A.,Ioffe, Sema L.,Tartakovsky, Vladimir A.
, p. 4584 - 4594 (2011/07/08)
A method for the introduction of a halogen atom into the methyl group attached to the C-3 atom of five- and six-membered cyclic nitronates (isoxazoline N-oxides and oxazine N-oxides, respectively) has been studied. The process involves silylation of start