1314234-24-6

Basic information

• Product Name: 6,8-difluoro-1,2,3-tris(3,5-difluorophenyl)naphthalene
• CAS NO: 1314234-24-6
• Molecular Weight: 500.391
• Mol File: 1314234-24-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6,8-difluoro-1,2,3-tris(3,5-difluorophenyl)naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: 6,8-difluoro-1,2,3-tris(3,5-difluorophenyl)naphthalene(1314234-24-6)
• EPA Substance Registry System: 6,8-difluoro-1,2,3-tris(3,5-difluorophenyl)naphthalene(1314234-24-6)

Safety Data

• Hazardous Substances Data: 1314234-24-6(Hazardous Substances Data)

Upstream product

• 1314234-16-6 1,2-bis(3,5-difluorophenyl)acetylene 

Relevant articles and documents

Palladium-catalyzed cycloisomerizations of diarylacetylenes: Synthesis, structures, and physical properties of highly substituted naphthalenes and 8,8 a-dihydrocyclopenta[a]indenes

Depending on the electronic properties of their substituents, the major products generated by palladium-catalyzed cycloisomerizations of diarylalkynes are either highly substituted 8,8a-dihydrocyclopenta[a]indenes 3 or naphthalenes 4. The structures of these compounds were verified by X-ray crystallographic analysis. Many functional groups tolerated the reaction conditions evaluated in this study. The isotope-labeled experiments indicated that added water has a critical role in forming both classes of compounds. The photophysical and electrochemical properties of cycloadducts 3 and their analogues were systematically studied and compared with computational predictions based on density functional theory. Dihydrocyclopenta[a]indenes 3 in either solid or liquid form display strong luminescence, whereas cyclopenta[a]indene 11 j is practically nonfluorescent. The functional groups directly attached to the backbone of compound 3 significantly influenced physical properties. The steric effect arising from the aryl substituents caused different luminescence phenomena, including aggregation-induced and -enhanced emission. Copyright