1315460-58-2Relevant articles and documents
Palladium-catalyzed elimination/isomerization of enol triflates into 1,3-dienes
Crouch, Ian T.,Dreier, Timothy,Frantz, Doug E.
supporting information; experimental part, p. 6128 - 6132 (2011/08/05)
Dying to be Dienes: Substituted 1,3-dienes were synthesized by the title reaction (see scheme; Tf=trifluoromethanesulfonyl). Preliminary studies support a mechanistically distinct pathway that involves an initial β-hydride elimination from a cationic vinyl palladium(II) intermediate, a subsequent regiospecific hydropalladation of the corresponding allene intermediate, and a final β-hydride elimination. Copyright
