1316844-18-4

Basic information

• Product Name: methyl 1-(2-bromobenzyl)-2,5-dimethyl-1H-pyrrole-3-carboxylate
• Synonyms: methyl 1-(2-bromobenzyl)-2,5-dimethyl-1H-pyrrole-3-carboxylate
• CAS NO: 1316844-18-4
• Molecular Weight: 322.202
• Mol File: 1316844-18-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 1-(2-bromobenzyl)-2,5-dimethyl-1H-pyrrole-3-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 1-(2-bromobenzyl)-2,5-dimethyl-1H-pyrrole-3-carboxylate(1316844-18-4)
• EPA Substance Registry System: methyl 1-(2-bromobenzyl)-2,5-dimethyl-1H-pyrrole-3-carboxylate(1316844-18-4)

Safety Data

• Hazardous Substances Data: 1316844-18-4(Hazardous Substances Data)

Upstream product

• 1316844-27-5 C₂H₃O₂^(1-)*C₂₁H₂₀BrINO₂⁽¹⁺⁾ 
• 69687-80-5 methyl 2,5-dimethyl-1H-pyrrole-3-carboxylate 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 

Downstream Products

• 1316844-41-3 methyl 4-(acetyloxy)-1-(2-bromobenzyl)-2,5-dimethyl-1H-pyrrole-3-carboxylate 
• 1316844-27-5 C₂H₃O₂^(1-)*C₂₁H₂₀BrINO₂⁽¹⁺⁾ 
• 1607826-99-2 methyl 1-(2-bromobenzyl)-2,5-dimethyl-4-morpholin-4-yl-1H-pyrrole-3-carboxylate 
• 1607826-98-1 methyl 1-(2-bromobenzyl)-4-[(4-bromophenyl)amino]-2,5-dimethyl-1H-pyrrole-3-carboxylate 

Relevant articles and documents

Iodonium salts are key intermediates in Pd-catalyzed acetoxylation of pyrroles

A mild, room-temperature Pd-catalyzed acetoxylation of pyrroles with phenyliodonium acetate is described. The acetoxylation was found to proceed via the initial formation of pyrrolyl(phenyl)iodonium acetates, which were converted to acetoxypyrroles in the presence of Pd(OAc)2. The acetoxylation could also be carried out as a one-pot sequential procedure without the isolation of the intermediate iodonium salts.