13210-18-9

Basic information

• Product Name: 9-(1'-ethoxycarbonyl-2'-oxo-3'-oxapent-1'-yl)xanthene
• Synonyms: 9-(1'-ethoxycarbonyl-2'-oxo-3'-oxapent-1'-yl)xanthene
• CAS NO: 13210-18-9
• Molecular Weight: 340.376
• Mol File: 13210-18-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9-(1'-ethoxycarbonyl-2'-oxo-3'-oxapent-1'-yl)xanthene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-(1'-ethoxycarbonyl-2'-oxo-3'-oxapent-1'-yl)xanthene(13210-18-9)
• EPA Substance Registry System: 9-(1'-ethoxycarbonyl-2'-oxo-3'-oxapent-1'-yl)xanthene(13210-18-9)

Safety Data

• Hazardous Substances Data: 13210-18-9(Hazardous Substances Data)

Upstream product

• 92-83-1 xanthene 
• 105-53-3 diethyl malonate 

Relevant articles and documents

Manganese(III)-Mediated Carbon-Carbon Bond Formation in the Reaction of Xanthenes with Active Methylene Compounds

Oxidation of xanthenes with manganese(III) acetate in the presence of active methylene compounds such as 1,3-dicarbonyl compounds, malononitrile derivatives, acetone, and nitromethane selectively gives 9-substituted xanthene derivatives in good yields.A similar oxidation of thioxanthene also yields 2-(9-thioxanthenyl)-1,3-dicarbonyl compounds in 57-91 percent yields.The obtained 2-(9-xanthenyl)-1,3-dicarbonyl compounds are readily converted to 2-(9-xanthenylidene)-1,3-dicarbonyl derivatives using manganese(III) complexes or 2,3-dichloro-5,6-dicyano-1,4-benzoquinone.The mechanisms for the formation of 9-substituted xanthenes are discussed on the basis of the reaction intermediates, the electron-donating substituent effect on the xanthene ring system, effect of additives, and comparison with a reaction of radical-trapping reagents.