1321619-44-6Relevant articles and documents
Ligand-free palladium-catalyzed Mizoroki-Heck reaction to synthesize valuable α-trifluoromethylacrylates
Bouillon, Jean-Philippe,Couve-Bonnaire, Samuel,Pannecoucke, Xavier,Schlinquer, Claire,Xiao, Pan
, (2020/03/03)
α-Trifluoromethylacrylates were synthesized using efficient ligand-free palladium catalyzed Mizoroki-Heck reaction. With the alkyl trifluoromethylacrylates used as substrates, different catalytic systems were explored including Pd/C as a catalyst. Good to excellent yields were obtained with good chemical tolerance.
A synthetic three fluoro methyl acrylic acid derivative method
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Paragraph 0024; 0088-0090, (2017/03/28)
The invention relates to a novel method for synthesizing a derivative of trifluoromethyl acrylic acid. In the method, a target product with yield of more than 80% can be obtained with commercial trifluoropropionic acid (or esters thereof) and aldehyde as