132454-69-4

Basic information

• Product Name: Trifluoro-methanesulfonic acid (3R,4R,5S)-5-benzyloxymethyl-4-methyl-2-oxo-tetrahydro-furan-3-yl ester
• CAS NO: 132454-69-4
• Molecular Weight: 368.331
• Mol File: 132454-69-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Trifluoro-methanesulfonic acid (3R,4R,5S)-5-benzyloxymethyl-4-methyl-2-oxo-tetrahydro-furan-3-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Trifluoro-methanesulfonic acid (3R,4R,5S)-5-benzyloxymethyl-4-methyl-2-oxo-tetrahydro-furan-3-yl ester(132454-69-4)
• EPA Substance Registry System: Trifluoro-methanesulfonic acid (3R,4R,5S)-5-benzyloxymethyl-4-methyl-2-oxo-tetrahydro-furan-3-yl ester(132454-69-4)

Safety Data

• Hazardous Substances Data: 132454-69-4(Hazardous Substances Data)

Upstream product

• 78785-15-6 3-deoxy-1,2-O-isopropylidene-3-C-methyl-α-D-ribo-pentodialdo-1,4-furanose 
• 109200-09-1 (S)-1-((3aR,5S,6R,6aR)-2,2,6-Trimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethane-1,2-diol 
• 30080-45-6 ((3aR,5S,6R,6aR)-2,2,6-trimethyl-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl)methanol 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 
• 26293-58-3 (3aR,5S,6R,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2,6-trimethyl-tetrahydrofuro[2,3-d][1,3]dioxole 
• 358-23-6 trifluoromethylsulfonic anhydride 
• 132454-70-7 3-Deoxy-3-C-methyl-D-ribonolactone 

Downstream Products

• 132454-74-1 Trifluoro-methanesulfonic acid (3S,4R,5S)-5-benzyloxymethyl-4-methyl-2-oxo-tetrahydro-furan-3-yl ester 
• 132490-20-1 (2S,3R,4R)-2,4-Bis-benzyloxymethyl-3-methyl-oxetane 
• 132454-83-2 (2S,4S)-2,4-Bis-benzyloxymethyl-3-methyl-oxetane 
• 132454-60-5 (2R,3R,4S)-4-Benzyloxymethyl-3-methyl-oxetane-2-carboxylic acid methyl ester 
• 132454-75-2 (3S,4S,5S)-5-Benzyloxymethyl-3-hydroxy-4-methyl-dihydro-furan-2-one 
• 132454-82-1 (2S,3R,4S)-4-Benzyloxymethyl-3-methyl-oxetane-2-carboxylic acid methyl ester 

Relevant articles and documents

Ring contraction of 3-deoxy-2-O-trifluoromethanesulphonates of α-hydroxy-γ-lactones to oxetanes

The ring contraction of α-triflates of 3-deoxy-1,4-lactones bearing hydrogen or alkyl substituents in the 3-position to methyl oxetane-2-carboxylates on treatment with potassium carbonate in methanol is described.