133205-53-5

Basic information

• Product Name: 2,2-dimethyl-4-phenyl-6-hexen-3-one
• Synonyms: 2,2-dimethyl-4-phenyl-6-hexen-3-one
• CAS NO: 133205-53-5
• Molecular Weight: 202.296
• Mol File: 133205-53-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,2-dimethyl-4-phenyl-6-hexen-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-dimethyl-4-phenyl-6-hexen-3-one(133205-53-5)
• EPA Substance Registry System: 2,2-dimethyl-4-phenyl-6-hexen-3-one(133205-53-5)

Safety Data

• Hazardous Substances Data: 133205-53-5(Hazardous Substances Data)

Upstream product

• 20971-19-1 (E)-2,2-dimethylhex-4-en-3-one 
• 507233-69-4 triphenyl bismuth ⁽²⁺⁾; dichloride 
• 3282-30-2 pivaloyl chloride 
• 2687-12-9 cinnamyl chloride 

Relevant articles and documents

Chemistry of Pentavalent Organobismuth Reagents. Regioselective α-Arylation of α,β-Unsaturated Carbonyls and Related Systems

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Synthesis and reactivity of allyl samarium complexes

Allyl chlorides react with SmCp2 to afford an allyl samarium intermediate, the η3-allyl structure of which has been tentatively assigned upon its reactivity with ketones. Synthesis of β,γ-unsaturated ketones have been also performed by reacting allyl samarium compounds with acid chlorides.