1335008-75-7

Basic information

• Product Name: 5-phenylsulfanyl-1,10-phenanthroline
• Synonyms: 5-phenylsulfanyl-1,10-phenanthroline
• CAS NO: 1335008-75-7
• Molecular Weight: 288.373
• Mol File: 1335008-75-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-phenylsulfanyl-1,10-phenanthroline(CAS DataBase Reference)
• NIST Chemistry Reference: 5-phenylsulfanyl-1,10-phenanthroline(1335008-75-7)
• EPA Substance Registry System: 5-phenylsulfanyl-1,10-phenanthroline(1335008-75-7)

Safety Data

• Hazardous Substances Data: 1335008-75-7(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 3188-84-9 1,2,3,4-tetrahydro-1,10-phenanthroline 
• 65115-91-5 5,6-epoxy-5,6-dihydro-[1,10]phenanthroline 

Relevant articles and documents

Site-Specific Oxidative C-H Chalcogenation of (Hetero)Aryl-Fused Cyclic Amines Enabled by Nanocobalt Oxides

By employing reusable nanocobalt oxides as the catalysts, a site-specific oxidative C-H chalcogenation of (hetero)aryl-fused cyclic amines with various thiols and diselenides is presented for the first time. The reaction proceeds selectively at the sites of the (hetero)aryl rings para to the N atom, and enables access to a wide array of chalcogenyl N-heteroarenes. The merits of the transformation involve high step- and atom-efficiency, excellent substrate and functional compatibility, operational simplicity, and the use of a naturally abundant Co/O2 system. The present work has offered a fundamental basis for the selective synthesis of functional N-heteroarenes from readily available feedstocks.