13361-67-6 Usage
Description
Dimethylaminotrimethylgermane, with the molecular formula (CH3)3NGe(CH3)2, is a colorless, flammable liquid characterized by a strong, ammonia-like odor. It is a chemical compound that plays a significant role in the field of organic synthesis and semiconductor material production.
Uses
Used in Semiconductor Material Production:
Dimethylaminotrimethylgermane is utilized as a reagent in the synthesis of germanium-based thin films, which are essential components in semiconductor materials. Its unique properties contribute to the development of advanced electronic devices and technologies.
Used in Organic Synthesis:
As a versatile reagent, dimethylaminotrimethylgermane is employed in various organic synthesis processes, enabling the creation of a wide range of chemical compounds.
Used in the Preparation of Organogermanium Compounds:
Dimethylaminotrimethylgermane serves as a key precursor in the preparation of other organogermanium compounds, which have diverse applications in different industries.
Used as a Catalyst in Chemical Reactions:
Due to its reactive nature, dimethylaminotrimethylgermane is used as a catalyst in certain chemical reactions, facilitating and enhancing the reaction processes.
Safety Precautions:
Given its flammability and potential for hazardous reactions when exposed to specific substances, dimethylaminotrimethylgermane should be handled with extreme caution to ensure safety in laboratory and industrial settings.
Check Digit Verification of cas no
The CAS Registry Mumber 13361-67-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,3,6 and 1 respectively; the second part has 2 digits, 6 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 13361-67:
(7*1)+(6*3)+(5*3)+(4*6)+(3*1)+(2*6)+(1*7)=86
86 % 10 = 6
So 13361-67-6 is a valid CAS Registry Number.
InChI:InChI=1/C3H9Ge.C2H6N/c1-4(2)3;1-3-2/h1-3H3;1-2H3/q;-1
13361-67-6Relevant articles and documents
A Heteroleptic Dirhodium Catalyst for Asymmetric Cyclopropanation with α-Stannyl α-Diazoacetate. “Stereoretentive” Stille Coupling with Formation of Chiral Quarternary Carbon Centers
Caló, Fabio P.,Fürstner, Alois
supporting information, p. 13900 - 13907 (2020/06/10)
The heteroleptic dirhodium paddlewheel catalyst 7 with a chiral carboxylate/acetamidate ligand sphere is uniquely effective in asymmetric [2+1] cycloadditions with α-diazo-α-trimethylstannyl (silyl, germyl) acetate. Originally discovered as a trace impurity in a sample of the homoleptic parent complex [Rh2((R)-TPCP)4] (5), it is shown that the protic acetamidate ligand is quintessential for rendering 7 highly enantioselective. The -NH group is thought to lock the ensuing metal carbene in place via interligand hydrogen bonding. The resulting stannylated cyclopropanes undergo “stereoretentive” cross coupling, which shows for the first time that even chiral quarternary carbon centers can be made by the Stille–Migita reaction.
