134680-68-5Relevant articles and documents
Sulfonate protecting groups. Synthesis of O- and C-methylated inositols: D- and L-ononitol, D- and L-laminitol, mytilitol and scyllo-inositol methyl ether
Sarmah, Manash P.,Shashidhar, Mysore S.,Sureshan, Kana M.,Gonnade, Rajesh G.,Bhadbhade, Mohan M.
, p. 4437 - 4446 (2007/10/03)
Syntheses of d- and l-ononitol, d- and l-laminitol, mytilitol and scyllo-inositol methyl ether starting from myo-inositol are described. One or two of the myo-inositol 1,3,5-orthoformate hydroxyl groups were protected as tosylates. These mono or ditosylat
TOTAL SYNTHESIS OF (-)-LAMINITOL (1D-4C-METHYL-myo-INOSITOL) VIA MICROBIAL OXIDATION OF TOLUENE
Carless, Howard A. J.,Oak, Ozer Z.
, p. 1671 - 1674 (2007/10/02)
The chiral cyclohexadienediol (4), available from oxidation of toluene by Pseudomonas putida, can be converted via selective epoxidation and ring-opening to the C-methyl conduritol F (8) and thence to (-) laminitol (2).