135-01-3Relevant articles and documents
Seyferth,White
, p. 119,120 (1972)
Method for simultaneously synthesizing methyl-ethylbenzene and diethylbenzene by virtue of one-step method
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Paragraph 0051-0065, (2016/12/22)
The invention relates to a method for simultaneously synthesizing methyl-ethylbenzene and diethylbenzene by virtue of a one-step method. Ethylene, benzene and methylbenzene are taken as raw materials to perform an alkylation reaction so as to synthesize methyl-ethylbenzene and diethylbenzene in one step. The method comprises a pretreatment stage, a reaction stage and an aftertreatment stage. In the method, one reaction system is adopted, and alkylation reaction and aftertreatment are sequentially performed so as to separate components, so that target products are obtained, and thus one-step simultaneous synthesis of methyl-ethylbenzene and diethylbenzene is realized; the problem that two independent devices are respectively used for production in a traditional production process is avoided, and the whole reaction process is convenient and rapid; the yields of different components can be effectively adjusted by adjusting different proportions of raw materials, and unreacted benzene and methylbenzene and the ethylbenzene generated in a reaction process are separated and recycled to serve as raw materials once again, so that the production cost is greatly saved, and meanwhile, the method can adapt to variations of the market to the greatest extent.
Synthesis, characterization and application of MCM-22 zeolites via a conventional HMI route and temperature-controlled phase transfer hydrothermal synthesis
Xing, Enhui,Shi, Yanchun,Xie, Wenhua,Zhang, Fengmei,Mu, Xuhong,Shu, Xingtian
, p. 8514 - 8522 (2015/03/05)
With less environmental and economical impact, temperature-controlled phase transfer hydrothermal synthesis of MWW zeolites was realized with hexamethyleneimine as a structure-directing agent and aniline as a structure-promoting agent. MCM-22 zeolite, synthesized via temperature-controlled phase transfer hydrothermal synthesis, is nearly identical concerning chemical composition and structure, and possesses nearly identical properties with respect to porosity, Si/Al ratio, thermal behavior and catalytic activity at 200°C, compared with that made from conventional synthesis with hexamethyleneimine as the only template.
Size-controlled synthesis of MCM-49 zeolites and their application in liquid-phase alkylation of benzene with ethylene
Shi, Yanchun,Xing, Enhui,Xie, Wenhua,Zhang, Fengmei,Mu, Xuhong,Shu, Xingtian
, p. 13420 - 13429 (2015/02/19)
Size-controlled synthesis of MCM-49 zeolites was achieved via topology reconstruction from NaY zeolites with different sizes. SEM images showed that the sizes of the reconstructed H-MCM-49 zeolites were controlled by those of the parent NaY zeolites. Smal
