135-13-7Relevant articles and documents
Emission Control of a Pyrene-thioindigo Compound
Saika, Tetsuyuki,Iyoda, Tomokazu,Honda, Kenichi,Shimidzu, Takeo
, p. 591 - 592 (1992)
Two distinct fluorescence modes of a thioindigo compound substituted with two pyrene groups on the 7 and 7' positions were controlled by geometrical photoisomerization of the thioindigo skeleton.
A General Way to Construct Arene-Fused Seven-Membered Nitrogen Heterocycles
Bakulina, Olga,Chizhova, Maria,Dar'in, Dmitry,Krasavin, Mikhail
supporting information, p. 362 - 371 (2018/01/27)
Imines react with seven-membered cyclic anhydrides (prepared from the corresponding dicarboxylic acids by a recently discovered in-situ cyclodehydration protocol) by the Castagnoli–Cushman reaction pathway to give privileged seven-membered arene-fused nitrogen-heterocyclic compounds with reagent-controlled diversity of the skeleton and peripheral groups.
An unexpected triethylsilane-triggered rearrangement of thioaurones to thioflavonols under SPPS conditions
Varedian, Miranda,Langer, Vratislav,Bergquist, Jonas,Gogoll, Adolf
supporting information; experimental part, p. 6033 - 6035 (2009/04/11)
Thioaurones are converted to a mixture of thiaindenes and thioflavonols when exposed to reaction conditions employed in SPPS, that is, treatment with trifluoroacetic acid in the presence of triethylsilane.
Metallation reactions. Part 35: A change of the regiochemistry in the metallation of (alkylthio)arenes
Cabiddu, Maria G.,Cabiddu, Salvatore,Cadoni, Enzo,De Montis, Stefania,Fattuoni, Claudia,Melis, Stefana
, p. 3915 - 3920 (2007/10/03)
The metallation reaction of bromo(alkylthio)benzenes is described. The results show the complementarity of these reactions with the metal-hydrogen exchange reaction. In fact, monometallation of bromo(methylthio)benzenes afforded products substituted in para or meta or ortho to the thioethereal function while bimetallation led to αS,para, αS,meta and αS,ortho disubstituted products. Analogously, the monometallation of 4-bromo-(isopropylthio)benzene afforded para-monosubstituted and ortho,para-disubstituted products.
