135094-36-9Relevant articles and documents
Evaluation of the chiral DIANANE backbone as ligand for organolithium reagents
Praz, Jezabel,Guenee, Laure,Aziz, Sarwar,Berkessel, Albrecht,Alexakis, Alexandre
scheme or table, p. 1780 - 1790 (2012/07/28)
Novel endo,endo-2,5-diaminonorbonane-derived tertiary C2- symmetrical diamines were synthesized via the one-pot reductive amination of enantiomerically pure norbornane-2,5-dione. These ligands were applied to various catalytic reactions such as asymmetric deprotonation, asymmetric bromine-lithium exchange, and enantioselective addition of aryl- and allkylithium reagents to aromatic aldimines. Copyright
Enantioselective Synthesis of DIANANE, a Novel C2-Symmetric Chiral Diamine for Asymmetric Catalysis
Berkessel, Albrecht,Schroeder, Michael,Sklorz, Christoph A.,Tabanella, Stefania,Vogl, Nadine,Lex, Johann,Neudoerfl, Joerg M.
, p. 3050 - 3056 (2007/10/03)
DIANANE (endo,endo-2,5-diaminonorbornane) is a novel chiral C 2-symmetric diamine, based on the rigid bicyclo[2.2.1]heptane scaffold. Schiff-base ligands derived from DIANANE have already found use in asymmetric catalysis, e.g., in the highly e
Syntheses in the isocamphane series XLII [1]. Synthesis and odour of 5-exo-hydroxycamphene (isonojigiku alcohol)
Buchbauer, Gerhard,Spreitzer, Helmut,Koller, Ursula,Bauer, Irmtraud,Wachter, Andreas
, p. 865 - 870 (2007/10/03)
The synthesis of the title compound is described. Hydroxylation of the endocyclic double bond of 2-acetyl-3,3-dimethylnorborn-5-ene furnished a mixture of nojigiku alcohol and the title compound. A shorter route leads from 2,5-norbornadiene solely to the desired camphoraceous smelling new hydroxy derivative to which the name isonojigiku alcohol is assigned.