1355061-82-3

Basic information

• Product Name: C₁₂H₁₅NO₂
• Synonyms: C₁₂H₁₅NO₂
• CAS NO: 1355061-82-3
• Molecular Weight: 205.257
• Mol File: 1355061-82-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₂H₁₅NO₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₂H₁₅NO₂(1355061-82-3)
• EPA Substance Registry System: C₁₂H₁₅NO₂(1355061-82-3)

Safety Data

• Hazardous Substances Data: 1355061-82-3(Hazardous Substances Data)

Upstream product

• 1866-39-3 4-methylcinnamic acid 
• 6638-79-5 N,O-dimethylhydroxylamine*hydrochloride 
• 104-87-0 4-methyl-benzaldehyde 

Downstream Products

• 132145-62-1 2-(p-tolyl)cyclopropanecarbaldehyde 
• 1422176-94-0 (1S,2S,3S)-2-(4-methylphenyl)-3-fluoro-N-methoxy-N-methyl-cyclopropanecarboxamide 

Relevant articles and documents

Radical-Cation Vinylcyclopropane Rearrangements by TiO2Photocatalysis

Radical cation vinylcyclopropane rearrangements by TiO2 photocatalysis in lithium perchlorate/nitromethane solution are described. The reactions are triggered by oxidative single electron transfer, which is followed by immediate ring-opening of the cyclopropanes to generate distonic radical cations as unique reactive intermediates. This approach can also be applied to vinylcyclobutane, leading to the construction of six-membered rings. A stepwise mechanism via distonic radical cations is proposed based on preliminary mechanistic studies, which is supported by density functional theory calculations.