1360457-10-8

Basic information

• Product Name: 1,3-di-tert-butyl-2-fluoro-2-(2,4,6-trimethylanilino)-4,4-dimethyl-1,3-diaza-2,4-disilacyclobutane
• CAS NO: 1360457-10-8
• Molecular Weight: 381.684
• Mol File: 1360457-10-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-di-tert-butyl-2-fluoro-2-(2,4,6-trimethylanilino)-4,4-dimethyl-1,3-diaza-2,4-disilacyclobutane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-di-tert-butyl-2-fluoro-2-(2,4,6-trimethylanilino)-4,4-dimethyl-1,3-diaza-2,4-disilacyclobutane(1360457-10-8)
• EPA Substance Registry System: 1,3-di-tert-butyl-2-fluoro-2-(2,4,6-trimethylanilino)-4,4-dimethyl-1,3-diaza-2,4-disilacyclobutane(1360457-10-8)

Safety Data

• Hazardous Substances Data: 1360457-10-8(Hazardous Substances Data)

Upstream product

• 1360457-04-0 1,3-di-tert-butyl-2,2-difluoro-4,4-dimethyl-1,3-diaza-2,4-disilacyclobutane 
• 65768-38-9 lithium 2,4,6-trimethylaniline 
• 17940-08-8 bis(tert-butylamino)dimethylsilane 

Relevant articles and documents

2-lithiumamide-2-fluoro-1,3-diaza-2,4-disilacyclobutanes- Syntheses, reactions, structures

The cyclodisilazane Me2Si(NCMe3)2SiF 2 (1) reacts with lithium salts of ammonia (2), hydrazine (3) and amines (4-10) to give the stable compounds Me2Si(NCMe 3)2SiFNHR (R = H (2), NH2 (3) CMe3 (4), C10H15 (5), 3,5-C6H3Me 2 (6), 2,4,6-C6H2Me3 (7), 2,6-C 6H3(CHMe2)2 (8), C6F 5 (9), Si(CMe3)2Ph (10)). Compounds 2-10 show no condensation reactions with formation of NH3, N2H 4, or amines. Dilithiummethylenediamide reacts with 1 to give the ethylenediamine coupled ring system 11 or spirocyclic compound 12. Compounds 2, 3, 4 form the spirocyclic systems 13-15 in reactions with n-C4H 9Li. A partly hydrolysed lithium salt (16) was isolated as tetramer containing a central Li6O octahedron. The lithium salts of 5 (17), 9 (19) and 10 (20) were isolated as monomers (17, 19) or dimer, respectively, via an (LiN)-four-membered ring (20). Crystal structures of 3, 9, 13-17, 19 and 20 are reported. Copyright