1365268-33-2Relevant articles and documents
Synthetic studies on (+)-bucidarasin C: Two diastereoselective transannular reactions producing cis-decaline derivatives that show reversal selectivity
Nakahara, Akinobu,Kanbe, Misaki,Nakada, Masahisa
scheme or table, p. 1518 - 1522 (2012/04/04)
This manuscript describes studies on the construction of the cis-decaline core of (+)-bucidarasin C. The transannular Diels-Alder (TADA) reaction of a macrocyclic lactone successfully afforded the desired cis-decaline derivative in a stereoselective manner. On the other hand, the stereoselective transannular cascade Michael (TACM) reaction of the parent macrocyclic lactone afforded the diastereomeric cis-decaline derivative as the major product.