1369277-21-3

Basic information

• Product Name: [RuCl(CO)(PPh₃)(2-(2-thiazolato)cresol(-H))]
• CAS NO: 1369277-21-3
• Molecular Weight: 645.083
• Mol File: 1369277-21-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [RuCl(CO)(PPh₃)(2-(2-thiazolato)cresol(-H))](CAS DataBase Reference)
• NIST Chemistry Reference: [RuCl(CO)(PPh₃)(2-(2-thiazolato)cresol(-H))](1369277-21-3)
• EPA Substance Registry System: [RuCl(CO)(PPh₃)(2-(2-thiazolato)cresol(-H))](1369277-21-3)

Safety Data

• Hazardous Substances Data: 1369277-21-3(Hazardous Substances Data)

Upstream product

• 157072-60-1 (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 1823-44-5 4-methyl-2-(thiazol-2-yl-diazenyl)phenol 

Relevant articles and documents

Ruthenium(II) NNO pincer type catalyst for the conversion of aldehydes to amides

The reaction of [RuHCl(CO)(PPh3)3] and 2-(2-thiazolylazo) cresol ligand (TAC) in benzene under reflux afforded a new pincer type ruthenium(II) carbonyl complex containing thiazolylazo cresol of general formula [RuCl(CO)(PPh3)(TAC)] (TAC = mono anionic NNO donor). The complex has been characterized by elemental analyses, FT-IR, UV-Vis, and 1H NMR spectral methods. The crystal structure of the complex [RuCl(CO)(PPh3)(TAC)] has been determined by single crystal X-ray diffraction which reveals the presence of a distorted octahedral geometry in the complex. The complex has been shown as an efficient catalyst for the conversion of aldehydes to amides in a one-pot process in the presence of NH 2OH?HCl/NaHCO3.