1370037-65-2Relevant articles and documents
Allylic carbon-carbon double bond directed pd-catalyzed oxidative ortho -olefination of arenes
Gandeepan, Parthasarathy,Cheng, Chien-Hong
supporting information; experimental part, p. 5738 - 5741 (2012/05/07)
Pd-catalyzed selective ortho-olefination of arenes assisted by an allylic C-C double bond at room temperature using O2 as a terminal oxidant is described. A possible mechanism involving the initial coordination of allylic C=C bond to Pd followed by selective o-C-H bond metalation is proposed.