137446-81-2Relevant articles and documents
Novel 1,3,4-oxadiazole thioether derivatives containing flexible-chain moiety: Design, synthesis, nematocidal activities, and pesticide-likeness analysis
Chen, Jixiang,Hu, Deyu,Luo, Yuqin,Song, Baoan,Wei, Chengqian,Wu, Rong,Wu, Sikai
supporting information, (2020/02/27)
Seventy-two novel 1,3,4-oxadiazole thioether derivatives containing different flexible-chain moieties were designed and synthesized. The nematicidal activities of all the title compounds were evaluated, and some compounds showed excellent nematicidal acti
CeCl3/Sm induced reductive cleavage of the S-S bond in disulfide: A novel method for the synthesis of β-thioesters, thiol-esters and alkylphenyl sulfides
Li, Xue,Zhang, Songlin,Zhang, Yongmin
, p. 1527 - 1529 (2007/10/03)
Disulfide has been reduced by cerium trichloride and samarium in tetrahydrofuran to produce samarium thiolates. The "living" species reacts smoothly with α,β-unsaturated esters(nitriles) to afford β-thioesters(nitrile) under mild and neutral conditions. The new thiolate anion also reacts with acyl halides, anhydrides and alkyl or benzyl halides to give thioesters and sulfides, respectively.
Lewis acid-promoted alkylations of arenes and 1-trimethylsilylalkynes with β-chloro-β-thiopropanoic esters
Ishibashi,Mino,Sakata,Inada,Ikeda
, p. 1148 - 1151 (2007/10/02)
Ethyl 3-chloro-3-(3,4-dichlorophenylthio)propanoate (8) reacted with electron-rich arenes in the presence of titanium tetrachloride to give the Friedel-Crafts products 10a-13a. Reactions of 8 with 1-trimethylsilylalkynes 14a-d were effected with aluminum chloride to afford the substitution products 15a-d. Some chemical transformations of the products are also described.
