137447-15-5

Basic information

• Product Name: Benzenamine, 2-(1H-perimidin-2-yl)-
• CAS NO: 137447-15-5
• Molecular Formula: C17H13N3
• Molecular Weight: 259.31
• Mol File: 137447-15-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzenamine, 2-(1H-perimidin-2-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 2-(1H-perimidin-2-yl)-(137447-15-5)
• EPA Substance Registry System: Benzenamine, 2-(1H-perimidin-2-yl)-(137447-15-5)

Safety Data

• Hazardous Substances Data: 137447-15-5(Hazardous Substances Data)

Upstream product

• 137447-29-1 2-(2-nitrophenyl)permidine 
• 118-48-9 isatoic anhydride 
• 479-27-6 naphthalene-1,8-diamine 

Downstream Products

• 137447-21-3 C₂₅H₁₇N₃O 
• 137447-32-6 2-<2-(2-chloro-2-phenylacetamido)phenyl>perimidine 
• 143883-01-6 13-(4-Chloro-2-nitro-phenyl)-12,13-dihydro-7,12,13a-triaza-benzo[hi]chrysene 
• 143883-00-5 13-(4-Methyl-2-nitro-phenyl)-12,13-dihydro-7,12,13a-triaza-benzo[hi]chrysene 
• 143883-02-7 13-(4,5-Dimethoxy-2-nitro-phenyl)-12,13-dihydro-7,12,13a-triaza-benzo[hi]chrysene 
• 137447-31-5 2-<2-(2-chloropropanamido)phenyl>perimidine 
• 143882-99-9 5,6-dihydro-6-(2-nitrophenyl)quinazolino<3,4-a>perimidine 
• 180972-62-7 N-(7,12,13a-Triaza-benzo[hi]chrysen-13-yl)-benzimidic acid 
• 143883-04-9 13-(2-Nitro-phenyl)-7,12,13a-triaza-benzo[hi]chrysene 

Relevant articles and documents

Nickel-Catalyzed Aerobic Oxidative Isocyanide Insertion: Access to Benzimidazoquinazoline Derivatives via a Sequential Double Annulation Cascade (SDAC) Strategy

An efficient protocol for the synthesis of quinazoline derivatives through nickel-catalyzed ligand-/base-free oxidative isocyanide insertion under aerobic conditions with intramolecular bis-amine nucleophiles has been developed. A one-pot sequential double annulation cascade (SDAC) strategy involving an opening of isatoic anhydride and annulation to benzimidazole and further nickel-catalyzed intramolecular isocyanide insertion has also been demonstrated. The method is operationally simple to implement with a wide variety of substrates and represents a new approach for multiple C-N bond formations. The methodology has been successfully applied to the syntheses of hitherto unreported imidazo-fused benzimidazoquinazolines via a deprotection-GBB reaction sequence. Further, a florescence study reveals the potential of the present strategy for the discovery of highly fluorescent probes.