13765-45-2Relevant articles and documents
GeHx (x=0-3) and GenHx (n=2-7) in flash pyrolysis of GeH4
Chambreau, Steven D.,Zhang, Jingsong
, p. 171 - 177 (2002)
Gas-phase thermal decomposition of germane, GeH4, has been studied using a flash pyrolysis technique (～ 20 μs reaction time), coupled with a vacuum-ultraviolet (VUV) photoionization time-of-flight mass spectrometer (TOFMS). Pyrolysis temperatures ranged from 685 to 1500 K, and resulted in the formation of GeH2 above 900 K and GeHx (x = 0, 1, 3) above 1100 K. In addition, Gen (n=2-7) and a small amount of highly unsaturated hydrogenated GenHx (n=2-7) clusters were observed above 1100 K.
Infrared spectra of group 14 hydrides in solid hydrogen: Experimental observation of Pbh4, Pb2H2, and Pb2H4
Wang, Xuefeng,Andrews, Lester
, p. 6581 - 6587 (2007/10/03)
Laser-ablated Si, Ge, Sn, and Pb atoms have been co-deposited with pure hydrogen at 3.5 K to form the group 14 hydrides. The initial SiH2 product reacts completely to SiH4, whereas substantial proportions of GeH2, SnH
