137776-67-1

Basic information

• Product Name: (1S,4R,5S,6R)-4,5,6-Trihydroxy-cyclohex-2-enecarboxylic acid methyl ester
• CAS NO: 137776-67-1
• Molecular Weight: 188.18
• Mol File: 137776-67-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,4R,5S,6R)-4,5,6-Trihydroxy-cyclohex-2-enecarboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,4R,5S,6R)-4,5,6-Trihydroxy-cyclohex-2-enecarboxylic acid methyl ester(137776-67-1)
• EPA Substance Registry System: (1S,4R,5S,6R)-4,5,6-Trihydroxy-cyclohex-2-enecarboxylic acid methyl ester(137776-67-1)

Safety Data

• Hazardous Substances Data: 137776-67-1(Hazardous Substances Data)

Upstream product

• 104184-64-7 3-Bromo-5,6-dihydro-2H-pyran-2-one 
• 134593-84-3 endo-1-bromo-4,4-dimethyl-3,5,8-trioxatricyclo[5.2.2.0]undec-10-en-9-one 
• 19978-32-6 3-bromo-2H-pyran-2-one 
• 67-56-1 methanol 
• 137776-66-0 (1RS,2SR,6SR,7SR)-4,4-dimethyl-3,5,8-trioxatricyclo<5.2.2.0^2,6>undec-10-en-9-one 
• 137776-72-8 3,5-dibromo-5,6-dihydro-2H-pyran-2-one 
• 3393-45-1 5,6-dihydro-pyran-2-one 

Relevant articles and documents

3-BROMO-2-PYRONE: AN EASILY PREPARED CHAMELEON DIENE AND A SYNTHETIC EQUIVALENT OF 2-PYRONE IN THERMAL DIELS-ALDER CYCLOADDITIONS

3-Bromo-2-pyrone, a stable solid prepared by a new route (eq. 1), has been found to undergo smooth and regiospecific 2+4-cycloadditions between 78-90 deg C with both electron-rich and electron-deficient dienophiles; subsequent high-yield reductive debromi