1377813-86-9Relevant articles and documents
TBN-mediated regio- and stereoselective sulfonylation & oximation (oximosulfonylation) of alkynes with sulfonyl hydrazines in EtOH/H2O
Wang, Bin,Yan, Zicong,Liu, Liyan,Wang, Jiawei,Zha, Zhenggen,Wang, Zhiyong
supporting information, p. 205 - 212 (2019/01/28)
An alkyne difunctionalization cascade reaction was developed to generate α-sulfonylethanone oximes under metal-free conditions. The reaction features environmentally benign EtOH/H2O as a solvent, a broad substrate scope and easily scaled up for gram-scale synthesis. The reaction mechanism was illustrated with UPLC, GC-MS and UPLC-tof/MS.