1380918-98-8

Basic information

• Product Name: (2,6-difluorophenyl)zinc(II) bromide
• Synonyms: (2,6-difluorophenyl)zinc(II) bromide
• CAS NO: 1380918-98-8
• Molecular Weight: 258.381
• Mol File: 1380918-98-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2,6-difluorophenyl)zinc(II) bromide(CAS DataBase Reference)
• NIST Chemistry Reference: (2,6-difluorophenyl)zinc(II) bromide(1380918-98-8)
• EPA Substance Registry System: (2,6-difluorophenyl)zinc(II) bromide(1380918-98-8)

Safety Data

• Hazardous Substances Data: 1380918-98-8(Hazardous Substances Data)

Upstream product

• 64248-56-2 1-bromo-2,6-difluorobenzene 
• 7699-45-8 zinc dibromide 

Downstream Products

• 1452489-27-8 methyl (E)-3-(2-(N-(1-(2,6-difluorophenyl)hexan-2-yl)sulfamoyl)phenyl)acrylate 
• 1452489-28-9 methyl (E)-3-(2-(N-(2-(2,6-difluorophenyl)hexyl)sulfamoyl)phenyl)acrylate 
• 1405127-62-9 3-(2,6-difluorophenyl)-6-methylpyridazine 
• 1405126-96-6 (S)-N-(4-(3-aminopiperidin-1-yl)pyridin-3-yl)-6-(2,6-difluorophenyl)-[1,2,4]triazolo[4,3-b]pyridazin-3-amine 2,2,2-trifluoroacetate 

Relevant articles and documents

Directed nickel-catalyzed negishi cross coupling of alkyl aziridines

Herein we report a nickel-catalyzed C-C bond-forming reaction between simple alkyl aziridines and organozinc reagents. This method represents the first catalytic cross-coupling reaction employing a nonallylic and nonbenzylic Csp3-N bond as an electrophile. Key to its success is the use of a new N-protecting group (cinsyl or Cn) bearing an electron-deficient olefin that directs oxidative addition and facilitates reductive elimination. Studies pertinent to elucidation of the mechanism of cross coupling are also presented.