13863-27-9

Basic information

• Product Name: 1-[2-(3,5-dimethylphenyl)vinyl]-3,5-dimethylbenzene
• Synonyms: 1-[2-(3,5-dimethylphenyl)vinyl]-3,5-dimethylbenzene
• CAS NO: 13863-27-9
• Molecular Formula: C₁₈H₂₀
• Molecular Weight: 236.3514
• Mol File: 13863-27-9.mol
• Article Data: 13

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-[2-(3,5-dimethylphenyl)vinyl]-3,5-dimethylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-[2-(3,5-dimethylphenyl)vinyl]-3,5-dimethylbenzene(13863-27-9)
• EPA Substance Registry System: 1-[2-(3,5-dimethylphenyl)vinyl]-3,5-dimethylbenzene(13863-27-9)

Safety Data

• Hazardous Substances Data: 13863-27-9(Hazardous Substances Data)

Upstream product

• 34696-73-6 3,5-dimethyphenylmagnesium bromide 
• 107146-56-5 1,2-bis(3,5-dimethylphenyl)acetylene 
• 27129-86-8 1-bromomethyl-3,5-dimethylbenzene 
• 5779-95-3 3,5-dimethylbenzaldehyde 
• 156-60-5 trans-1,2-dichloroethylene 
• 172975-69-8 3,5-dimethylphenyl boronic acid 
• 91110-69-9 1,3-dimethyl-5-[(phenylsulfonyl)methyl]benzene 
• 52988-36-0 triphenyl(3,5-dimethylbenzyl)phosphonium bromide 

Downstream Products

• 158391-63-0 (R,R)-(+)-1,2-bis(3,5-dimethylphenyl)ethane-1,2-diol 
• 196605-90-0 (S,S)-(+)-1,2-bis(3,5-dimethylphenyl)ethane-1,2-diol 
• 158391-64-1 (S,S)-1,2-diazido-1,2-bis(3,5-dimethylphenyl)ethane 
• 187981-04-0 Methanesulfonic acid (1R,2R)-1,2-bis-(3,5-dimethyl-phenyl)-2-methanesulfonyloxy-ethyl ester 
• 158391-59-4 (1S,2S)-1,2-bis (3,5-di-tert-butylphenyl)ethane-1,2-diamine 
• 866044-17-9 (1R,2R)-1,2-N,N'-bis(p-toluenesulfonylamino)-1,2-bis(3,5-dimethylphenyl)ethane 
• 866044-13-5 (R,R)-1,2-diazido-1,2-bis(3,5-dimethylphenyl)ethane 
• 503112-15-0 (1R,2R)-1,2-bis(3,5-dimethylphenyl)ethane-1,2-diamine 
• 7396-38-5 2,4,5,7-tetramethylphenanthrene 

Relevant articles and documents

Structural requirements for palladium catalyst transfer on a carbon-carbon double bond

Intramolecular transfer of tBu3PPd(0) on a carbon-carbon double bond (C=C) was investigated by using Suzuki-Miyaura coupling reaction of dibromostilbenes with aryl boronic acid or boronic acid esters in the presence of various additi

AIR-STABLE NI(0)-OLEFIN COMPLEXES AND THEIR USE AS CATALYSTS OR PRECATALYSTS

The present invention relates to air stable, binary Ni(0)-olefin complexes and their use in organic synthesis.

Ni(4?Tbustb)3: A robust 16-electron Ni(0) olefin complex for catalysis

Sixteen-electron Ni(0) complexes bearing trans-stilbene derivative ligands have been shown to display a high degree of stability toward oxidation in the solid state. A structural analysis of a unique family of tris Ni(0) stilbene complexes revealed a remarkable effect of the steric hindrance of the substituents at the para position of the stilbene unit to temperature, oxidation, and degradation in solution. From these analyses, Ni(4?tBustb)3 arose as a long-term air-, bench-. and temperature-stable Ni(0) complex. Importantly, Ni(4?tBustb)3 presents faster kinetic profiles and a broader scope as a Ni(0) source, thus outperforming the previously described Ni(4?CF3stb)3 in a variety of relevant Ni-catalyzed transformations.

Ethylaluminum as an ethylene source for the Mizoroki-Heck-type reaction. Rhodium-catalyzed preparation of stilbene derivatives

Treatment of an organoaluminum reagent bearing aryl and ethyl groups furnishes 1,2-diarylethene derivatives in good to excellent yields by the catalysis of a rhodium complex, in which the ethyl group of the aluminum reagent serves as an ethylene source in the product formation.