139025-77-7

Basic information

• Product Name: 2-((E)-1-Hydroxy-but-2-enyl)-2-methyl-cyclohexanone
• CAS NO: 139025-77-7
• Molecular Weight: 182.263
• Mol File: 139025-77-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-((E)-1-Hydroxy-but-2-enyl)-2-methyl-cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-((E)-1-Hydroxy-but-2-enyl)-2-methyl-cyclohexanone(139025-77-7)
• EPA Substance Registry System: 2-((E)-1-Hydroxy-but-2-enyl)-2-methyl-cyclohexanone(139025-77-7)

Safety Data

• Hazardous Substances Data: 139025-77-7(Hazardous Substances Data)

Upstream product

• 7770-41-4 1-methyl-2-oxocyclohexanecarboxylic acid 2-propenyl ester 
• 123-73-9 crotonaldehyde 

Relevant articles and documents

NiCl2(PPh3)2-Zn Promoted Deallyloxycarbonylative Directed Aldol Reaction of Allyl β-Keto Carboxylates with Aldehydes th β-Hydroxy Ketones

Regio- and chemospecific deallyloxycarbonylative aldol reaction of allyl (or -lic) α,α-disubstituted β-keto carboxylate with aldehyde was effectively promoted by Ni(0) (NiCl2(PPh3)2-Zn), in which the allyloxycarbonyl group (-COOCH2CH=CH2) was replaced to 1-hydroxyalkyl group (-CH(OH)R, R=alkyl, vinyl, aryl) under mild reaction conditions.