139199-72-7

Basic information

• Product Name: (3S)-nonan-3-yl (2R)-3,3,3-trifluoro-2-methoxy-2-phenylpropanoate
• Synonyms: (3S)-nonan-3-yl (2R)-3,3,3-trifluoro-2-methoxy-2-phenylpropanoate
• CAS NO: 139199-72-7
• Molecular Weight: 360.417
• Mol File: 139199-72-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (3S)-nonan-3-yl (2R)-3,3,3-trifluoro-2-methoxy-2-phenylpropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (3S)-nonan-3-yl (2R)-3,3,3-trifluoro-2-methoxy-2-phenylpropanoate(139199-72-7)
• EPA Substance Registry System: (3S)-nonan-3-yl (2R)-3,3,3-trifluoro-2-methoxy-2-phenylpropanoate(139199-72-7)

Safety Data

• Hazardous Substances Data: 139199-72-7(Hazardous Substances Data)

Upstream product

• 61925-49-3 (S)-nonan-3-ol 
• 20445-33-4 (R)-methoxytrifluoromethylphenylacetyl chloride 
• 185019-15-2 nonan-3-ol 
• 20445-31-2 R-(+)-α-trifluoromethyl-α-methoxy-phenylacetic acid 

Relevant articles and documents

Novel C2-symmetric chiral O,N,N,O-tetradentate 2,2-bipyridyldiolpropane ligands: Synthesis and application in asymmetric diethylzinc addition to aldehydes

First synthesis of C2-symmetric chiral O,N,N,O-tetradentate 2,2-bipyridyldiolpropane ligands is described. The Mukaiyama-Michael reaction was applied as an important reaction for the synthesis of 2,2-bipyridylpropane 9. Among the ligands synthesized, ligand 11 exhibits excellent chiral induction (up to 97% ee) in diethylzinc addition to various aldehydes. The use of additional Lewis acid such as Ti(OiPr)4 in diethylzinc addition reaction is not required for the present catalytic system.

Enantioselective transfer hydrogenation of aliphatic ketones catalyzed by ruthenium complexes linked to the secondary face of β-cyclodextrin

Ruthenium-η-arene complexes attached to the secondary face of β-cyclodextrin catalyze the enantioselective reduction (ee up to 98%) of aliphatic and aromatic ketones in aqueous medium in the presence of sodium formate (HCOONa).