13927-77-0

Basic information

• Product Name: Nickel dibutyldithiocarbamate
• Synonyms: VANOX NBC;NICKEL(II) BIS(DIBUTYLDITHIOCARBAMATE);NICKEL DI-N-BUTYLDITHIOCARBAMATE;NICKEL DIBUTYL DITHIOCARBAMATE;NDBC;DI-N-BUTYLDITHIOCARBAMIC ACID NICKEL SALT;bis(dibutyldithiocarbamate)nickel complex;BIS(DIBUTYLDITHIOCARBAMATO)NICKEL
• CAS NO: 13927-77-0
• Molecular Formula: C₁₈H₃₆N₂NiS₄
• Molecular Weight: 467.45
• EINECS: 237-696-2
• Product Categories: Organometallics;Classes of Metal Compounds;Ni (Nickel) Compounds;Transition Metal Compounds
• Mol File: 13927-77-0.mol
• Article Data: 1

Chemical Properties

• Melting Point: 86°C
• Boiling Point: 450.81°C (estimate)
• Flash Point: 260°C
• Appearance: COA
• Density: 1,26 g/cm3
• Vapor Pressure: 0.0144mmHg at 25°C
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Solubility: Practically insoluble in water
• Water Solubility: 8.93μg/L at 20℃
• CAS DataBase Reference: Nickel dibutyldithiocarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: Nickel dibutyldithiocarbamate(13927-77-0)
• EPA Substance Registry System: Nickel dibutyldithiocarbamate(13927-77-0)

Safety Data

• RTECS: QR6140000
• TSCA: Yes
• Hazardous Substances Data: 13927-77-0(Hazardous Substances Data)

Usage

Chemical Properties

Dark-green flakes.

Uses

Antioxidant for synthetic rubbers.

Flammability and Explosibility

Notclassified

Safety Profile

Low toxicity by ingestion.Confirmed human carcinogen with experimentaltumorigenic data.

InChI:InChI=1/2C9H19NS2.Ni/c2*1-3-5-7-10(9(11)12)8-6-4-2;/h2*3-8H2,1-2H3,(H,11,12);/q;;+2/p-2

Upstream product

• 75-15-0 carbon disulfide 
• 111-92-2 dibutylamine 
• 7440-02-0 nickel 
• 136-30-1 sodium dibutyl dithiocarbamate 
• 25749-24-0 tris(dibutyldithiocarbamato)nickel(IV) bromide 

Downstream Products

• 12255-10-6 gersdorffite 

Relevant articles and documents

Structural organization of nickel(II), zinc(II), and copper(II) complexes with diisobutyldithiocarbamate: EPR, 13C and 15N CP/MAS NMR, and X-ray diffraction studies

The structures and spectroscopic properties of nickel(II), zinc(II), and copper(II) complexes with dibutyl- and diisobutyldithiocarbamate were studied by EPR and 13C and 15N CP/MAS NMR spectroscopy and X-ray diffraction analysis. According to the EPR data, copper(II) forms mononuclear [63/65Cu{S2CNR2}2] and heterobinuclear complexes [63/65CuZn{S2CNR 2}4] under magnetic dilution conditions. The isomeric forms of nickel(II) and zinc(II) diisobutyldithiocarbamates were detected by 13C and 15N NMR spectroscopy. The crystalline zinc(II) diisobutyldithiocarbamate was found to have a unique structural organization with alternating mononuclear [Zn{S2CN(i-C4H 9)2}2] and binuclear molecular forms [Zn 2{ S2CN(i-C4H9)2} 4] in the 1 : 1 ratio.